Canyon Materials, Inc.














Canyon Materials, Inc. specializes in the fabrication of true gray scale photomasks for use in gray scale photolithography to produce 3-D microstructures, see U.S. Patent No. 6,562,523B1 and No. 6,524,756B1. E-beam written HEBS-glass photomasks and laser beam written LDW-glass photomasks are TRUE gray scale photomasks (NOT halftone masks). Customers' designed 3D microstructures are manufactured using an all-glass gray scale photomask wherein a gray scale pattern having a number of gray levels eg. from 2 up to more than 500 gray levels is written with an electron beam (e-beam) or a laser beam pattern generator. The mask pattern is written within a surface glass layer of the all-glass photomask, i.e. no coating of any kind. Each 0.1 micron spot or line of the mask pattern may be written with a pre-determined transmittance value. HEBS glass and LDW glass are patented glass products of Canyon Materials, Inc. HEBS-glass photomask blanks are the 1997 Photonic Circle of Excellence Award winner. See more about the award here. The all-glass gray scale photomasks enable mass fabrication of 3-D microstructures including refractive microlens arrays, diffractive optical elements (DOE), holographic devices, tapered structures for microelectronic and micromechanical devices, beam shaping elements, and much more. Successful optoelectronic consumer products and medical equipment containing key optical elements made with the use of all glass gray scale photomask technology have been growing in number in the world-wide market.

See how easily you can design your own microlens arrays and tapered structures using all-glass gray scale mask technology by reading CMI Product Information No. 01-88 "All-Glass Gray Scale Mask Technology"

CMI has e-beam writers in-house, available write grids are 25nm (i.e. 25 nanometer), 50nm, and 100nm. For good throughput and still very high gray scale resolution, HEBS-glass gray scale masks are typically written with a pixel size of 100nm (i.e. 0.1 micron). Within a 5"x5" pattern area, each of the gray pixels may have an optical density value or a transmittance value selected from more than 500 gray levels. The number of grayscale levels in a HEBS-glass mask is only limited by the accuracy and reproducibility of the clock rates of a vector scan e-beam writer. In the data file for writing an all-glass gray scale mask, each gray level is a layer. For example, a mask written with 100 layers of GDS data file is used to fabricate a 3D microstructure having 100 gray scale height levels.

HEBS-glass plates offer true gray scale photomasks with the highest gray scale resolution possible! CMI Product Information No. 04-100 decribes how All-glass gray scale photomasks offer the highest gray scale resolution when compared to alternative gray scale photomask techniques like halftone masks and photographic emulsion masks.

All-glass gray scale photomasks include HEBS-glass and LDW-glass masks. The all-glass gray scale photomasks which have no coating of any kind, do not have any abrupt change in refractive index in the mask patterns such as those exist in chrome line edges in the conventional chrome masks. As a matter of fact, the boundaries between clear and dark (e.g. chrome) halftone dots cause unwanted scattering or diffraction. Without the undesirable scattering or diffraction, a true gray scale optical density pattern in an all-glass mask is faithfully and reproducibly converted into a corresponding gray scale height pattern in photoresist through an otherwise conventional optical lithographic process, when the conventional binary mask is replaced by an all-glass gray scale mask.

Numerous all-glass gray scale masks (see exemplary masks) were made for a variety of applications.

Among many fabrication techniques that were used to produce microoptical elements, all-glass gray scale mask technology remains the most flexible, versitile, and accurate method. With an all-glass gray scale mask, the fabrication of microoptical elements uses conventional IC fabrication tools. Any existing model of contact aligners, projection printers, and reduction steppers designed for IC fabrication can be used in the gray scale photolithography using an all-glass photomask.

All-glass gray scale photomasks enable economic mass fabrication of 3D microstructures in photoresist, in fused silica, in silicon, and in visible, near infrared and infrared transmitting substrates. Moreover, even for the fabrication of just one mold surface for embossing and compression molding of plastic optical elements, photolithography using an all-glass gray scale photomask is preferred over e-beam or laser beam direct write on photoresist, for both quality and economic advantanges, see CMI Product Information No. 01-88.

Ultimate Quality CGHs - Computer generated holograms (CGHs) with many phase levels are produced from All-Glass Gray Scale Photomasks in one photolithographic step. A gray pixel in a random phase plate may be 0.1 micron, or much larger pixel sizes for economic reason.

Leading Edge Microlens Fabrication - All-glass masks enable users to create traditional as well as new designs of microlens arrays: e.g. 100% fill factor with square or hexagonal aperture, aspheric or spheric lenses, each lenslet in an array can be unique, e.g. Microlenses Designed with Varied Degree of Compound Tilt.

The micro-optical elements produced with an all-glass photomask are proven particularly effective to improve efficiency of imaging, collimation, beam splitting and funneling light into an active area in each pixel of an array, including, for example, a refractive microlens array with 100% fill factor for focusing light onto the optically active part in each detector cell of a CCD or a CMOS Imager, similarly, a refractive microlens array with 100% fill factor to funnel light through the transmissive region of each TFT transistor which turns each pixel in an LCD display on and off giving brighter images, a refractive microlens array for Shack-Hartman wavefront sensor, prealigned arrays of microlenses to collimate light from fibers or from laser diode sources, and much more.

Companies using all-glass photomasks include Panasonic Communications Co. Ltd., Panasonic Boston Laboratoty, ITRI of Taiwan, Advanced Medical Optics, Wavefront Sciences Inc., Rockwell Sciece Center, Seiko Epson, Canon, Nikon, NASA, Sandia National Laboratories, Ricoh, Sony, NTT Communications, Dong Jin Semichem Co. Ltd., Raytheon Company, Teledyne Scientific & Imagining, LLC, De La Rue Group of U.K., Olympus, Samsung, Samsung America, Inc., Alps, Epson, SII of Japan, Yamatake, Asahi, Samsung Electronics, Co., Ltd., Smithsoniam Observatory, Jet Propulsion Laboratories, among many others.

Incorporating grayscale optical elements, better quality consumer products are produced at lower cost. One such example, Panasonic Communications Co. Ltd. introduced in 2007 a 9.5mm height Ultra Slim Multi Drive incorporating a gray scale diffractive optic, as described in proceedings from ISDM-ODS 2008 Hawaii conference. With a non exclusive license from Canyon Materials, Inc. to use LDW-glass blanks to make a grayscale mask and to make a gray scale diffractive optic using the LDW glass gray scale photomask, Panasonic Communications Co. Ltd. (PCC) was the first to successfully mass-produce a 9.5mm height Ultra Slim Super Multi Drive incorporating the grayscale diffractive optic. The technology improved the signal quality by increasing diffraction efficiency of the diffractive optic and brought significant reduction of cost per drive as a result. The greatest technical improvement of the PCC drive is the use of gray scale optics to improve the diffraction efficiency to 85% from 32% of the older version of the PCC drive that used a conventional binary hologram. Gray scale photolithography using LDW-glass gray scale mask enabled mass-production in quality; the RMS shape error being less than 10mm, see fig. 4 of the paper, which can be downloaded here. LDW-glass mask was written using a laser writer similar to LW405 LaserWriter of Microtech.

A cost effective combination of LDW glass together with a laser writer, e.g. LW405 LaserWriter of Microtech, enables customers to produce quickly and with high quality their own gray scale photomasks in house. You may establish a nano-machine shop for the fabrication micro-optical elements by acquiring a laser writer to write your own LDW-glass gray scale photomasks.

Additional Utility of LDW glass - LDW glass may be used for micromachining of micro-optics in a LDW-glass plate using laser direct write followed by an etching step in HF solution to convert gray scale optical density levels in a LDW-glass plate into gray scale height levels in the LDW-glass plate.


----- CMI Products in Stock -----
LDW Glass Mask Blanks, see LDW Glass.
Choices of the optical density (OD) value of a LDW blank include 1.0, 1.1, 1.2, 1.3, 1.5, 2.0, 2.5, 3.0, and any other value of OD for custom ordered plates.

LDW Glass Mask Blank is a monolithic glass plate having a darkened surface glass layer of 1 micron thickness which has a desired optical density value corresponding to the maximum OD value of a predesigned gray scale mask pattern.

Useful properties include:

1. The darkened surface glass layer is heat erased and becomes transparent instantaneously when exposed to a focused laser beam. The transmittance of the surface glass layer increases with increasing laser beam writing energy density levels.

2. Due to a heat threshold effect only the tip of the Gaussian intensity profile of the laser focused spot causes heat erasure of the surface glass layer. The recorded spot on LDW glass plate is submicron in size even if the focused laser spot is substantially more than 1 micron. Smooth OD profile together with abrupt change in OD such as the profile of a blazed grating can be produced using a LDW-glass mask with a shape error of less than 10nm.

3. There exist a well known problem of laser direct write on photoresist due to the spot size of the laser beam, namely, a limit on shape accurancy and roughness exist in a mold surface which is fabricated using laser beam direct write on photoresist. This well known problem of laser beam direct write on photoresist does not exist in the gray scale pattern of LDW mask because of the heat threshold effect in the heat erasure mode of recoding on LDW glass plate.

4. Any in-house/existing contact aligner or projection printer or a stepper may be utilized for the fabrication of cutting edge microoptical products.

5. A dark field mask is more readily produced in a LDW mask, whereas a clear field mask is more readily produced in a HEBS-glass mask.

HEBS Glass Mask Blanks, see HEBS Glass.

HEBS-glass mask blank is a monolithic silicate glass plate having an e-beam darkenable surface glass layer. The surface glass layer is darkened instantaneously upon exposure to electron beam i.e. without any post exposure treatment. The optical density increases with increasing electron dosage. Every 0.1 micron spot/area in a HEBS-glass plate may have a predetermined transmittance value selected from 1000 or more transmittance values/levels.

Microstructures with smooth surface profiles, e.g. refractive microlens arrays and microprisms, are precisely fabricated with a HEBS-glass mask having a limited number of gray scale levels such as 16 to 64 levels.

CMI Calibration Plate HEBS5 for positive photoresist

Use a HEBS Glass Calibration Plate to perfect your gray scale photolithography process

Patterns included on HEBS5:
  • Resist thickness vs. OD calibration
  • Tapered & via structures
  • Microlens arrays (including 100% fill factor, array with each lens unique!)
  • Sinusoidal transmittance gratings

    Ask about our inexpensive test mask in 2.5" x 2.5" HEBS plate containing most of the test structures of Calibration Plate HEBS5.

    CMI Calibration Plates I85P+N and HEBS5N for negative resist & sol gel applications.

    Sinusoidal MTF Target
    HEBS-glass Sinusoidal Target contains sinusoidal gratings 2 to 500 periods per mm, this MTF Target having smooth and continuous OD profiles of sine waves, has no graniness and is less expensive than other commercially available products of much less quality.


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